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31.
Rivera D Granda S Arumí JL Sandoval M Billib M 《Environmental monitoring and assessment》2012,184(11):6563-6574
Soil moisture is the key link among hydroecological compartments, responding dynamically to sequences of atmospheric processes and management conditions and modulating physical, chemical, and biological processes in the soil. Currently, there are a variety of monitoring techniques to measure, directly or indirectly, the soil moisture. However, some practical issues remain open like the definition a priori of the number, location and depth of the monitoring points, and the impact of failing or poor performance soil moisture sensors. Here, we present a set of techniques, namely Δθ time series, wavelet filtering, and time stability, to identify representative points and monitoring depths through an analysis of hourly soil moisture time series for different configuration of the monitoring network. We used real data from a monitoring network consisting of seven monitoring points, each one with four EC-5 probes (Decagon Devices Inc., Pullman, WA) at 20, 40, 60, and 100?cm. The use of simple time series of Δθ allowed us to assess the spatiotemporal influence of the monitoring points, while the wavelet periodograms allowed us to get insight about the response of the monitoring points at different time scales. Both methods are easy to implement or adapt to specific conditions, being coherent to the results derived from time stability analysis. For our case study, we concluded that we could reallocate 16 sensors (out of 28) without a significant loss of information. However, the final decision strongly relies on a deep knowledge of the site features and the objectives of the monitoring network. 相似文献
32.
Héctor G. Riveros Javier Tejeda Luis Ortiz Adriana Julián-Sánchez Héctor Riveros-Rosas 《Journal of the Air & Waste Management Association (1995)》2013,63(12):973-984
Abstract In Mexico City, the use and composition of fuels determine that carbon monoxide (CO) comes mostly from mobile sources, and sulfur dioxide (SO2) from fixed and mobile sources. By simultaneously measuring hydrocarbons (HC), CO, and SO2 in the atmosphere of Mexico City, the relative amounts coming from different sources can be estimated. Assuming that some HC are emitted proportionally to CO emissions, we can establish that [HC]1= m1? [CO], where the proportionality constant ml corresponds to the ratio of emissions factor for HC and CO in mobile sources. Similarly for fuels containing sulfur, it can be assumed that [HC]2 = m2 ? [SO2]. In this way, the total HC are [HC]total=[HC]0+ ml ? [CO]+ m2 ? [SO2], where [HC]0 corresponds mainly to other sources like solvent evaporation, gas consumption, and natural emissions. In this way, it can be estimated that in Mexico City 75% of average HC comes from mobile sources, 5% from sulfur-related sources, and 19% from natural sources and solvent evaporation. Compared with the HC/CO ratio measured in the exhaust pipe of vehicles, we estimated that 70% of HC emitted from mobile sources are evaporative losses, and only 30% come through the exhaust system. 相似文献
33.
Luis Carlos Belalcazar Oliver Fuhrer Minh Dung Ho Erika Zarate Alain Clappier 《Atmospheric environment (Oxford, England : 1994)》2009,43(36):5830-5837
Road traffic emissions, one of the largest source categories in megacity inventories, are highly uncertain. It is essential to develop methodologies to reduce these uncertainties to manage air quality more effectively. In this paper, we propose a methodology to estimate road traffic emission factors (EFs) from a tracer experiment and from roadside pollutants measurements. We emitted continuously during about 300 non-consecutive hours a passive tracer from a finite line source placed on one site of an urban street. At the same time, we measured continuously the resulting tracer concentrations at the other side of the street with a portable on-line gas chromatograph. We used n-propane contained in commercial liquid petroleum gas (LPG) as a passive tracer. Propane offers several advantages to traditional tracers (SF6, N2O, CFCs): low price, easily available, non-reactive, negligible global warming potential, and easy to detect with commercial on-line gas chromatographs.The tracer experiment was carried out from January to March 2007 in a busy street of Ho Chi Minh City (Vietnam). Traffic volume, weather information and pollutant concentrations were also measured at the measurement site. We used the results of the tracer experiment to calculate the dilution factors and afterwards we used these dilution factors, the traffic counts and the pollutant concentrations to estimate the EFs. The proposed method assumes that the finite emission line represents the emission produced by traffic in the full area of the street and therefore there is an error associated to this assumption. We use the Computational Fluids Dynamics (CFD) model MISKAM to calculate this error and to correct the HCMC EFs. EFs for 15 volatile organic compounds (VOCs) and NO are reported here. A comparison with available studies reveals that most of the EFs estimated here are within the range of EFs reported in other studies. 相似文献
34.
Karina Martínez-Aguilar Eustacio Ramírez-Fuentes MA. Nieves Trujillo-Tapia Luis Alfredo Ortega-Clemente 《Journal of environmental science and health. Part. B》2013,48(12):771-776
AbstractMalathion is an organophosphorus pesticide widely used in agricultural crops, despite its toxicity. In addition, malaoxon occurs by oxidation of malathion being more toxic. The toxic effects of malathion and malaoxon in humans include hepatoxicity, breast cancer, genetic damage and endocrine disruption. The aim of this study involved assessing the effect of malathion commercial grade on Chroococcus sp., and its potential as an alternative to the removal of this pesticide and its transformation product such as malaoxon. We evaluated the effect of malathion at different concentrations (1, 25, 50, 75 and 100?ppm) on the biomass of the cyanobacteria Chroococcus sp. grown in medium BG-11; also, we analyse its ability to degrade both malathion and malaoxon into a temperature of 28?±?2?°C and at pH 6. The results showed that 50?ppm of malathion the cyanobacteria Chroococcus sp. reached the highest removal efficiency of malathion and malaoxon (69 and 65%, respectively); also, the growth rate of Chroococcus sp. increased without inhibiting the production of chlorophyll “a”, this can be explained by the hormesis phenomenon. Therefore, we consider that the cyanobacteria Chroococcus sp. may be a good candidate for bioremediation of aquatic systems contaminated with organophosphorus pesticides such as malathion and its transformation product such as malaoxon. 相似文献
35.
Linice Vasconcelos Cavalcante Bonaparte Antonio Tavernard Pereira Neto Luis Gonzaga Sales Vasconcelos Romildo Pereira Brito José Jaílson Nicácio Alves 《Process Safety and Environmental Protection》2010,88(5):372-379
This is a case study of contamination by a non-aqueous phase liquid (NAPL) that leaked from a chemical plant. The remediation procedure adopted for the initial phase of the plume migration was a plastic diaphragm wall coupled with a series of water extraction wells designed to avoid environmental impact on the surrounding ecosystems. Monitoring has shown that the containment is successful, and additional measures that contribute to accelerating remediation have been adopted. The authors wished to investigate how remediation might be further enhanced. The use of in situ aeration coupled with a system of soil vapor extraction (AS/SVE) has been chosen, since the remediation of sites with characteristics similar to those in this study, if based exclusively on dissolved-phase control, would take several decades to be completed. The transport of contaminant plumes has been simulated by using an analytical model to evaluate the effectiveness of the natural attenuation of the contaminant. The results of the simulation have confirmed the limited effectiveness of the natural attenuation of the contaminant, as well as the effective increase of remediation that would occur if the AS/SVE system is applied. A sensitivity analysis that included several combinations of increments of parameters that correspond to the decay rate of the source and the dissolved plume has simulated what might happen if the AS/SVE system is implemented. 相似文献
36.
Celia Arenas Carlos Leiva Luis F. Vilches Héctor Cifuentes 《Waste management (New York, N.Y.)》2013,33(11):2316-2321
The present study aims to determine and evaluate the applicability of a new product consisting of coal bottom ash mixed with Portland cement in the application of highway noise barriers. In order to effectively recycle the bottom ash, the influence of the grain particle size of bottom ash, the thickness of the panel and the combination of different layers with various particle sizes have been studied, as well as some environmental properties including leachability (EN-12457-4, NEN-7345) and radioactivity tests. Based on the obtained results, the acoustic properties of the final composite material were similar or even better than those found in porous concrete used for the same application. According to this study, the material produced presented no environmental risk. 相似文献
37.
Hector Gutierrez-Bañuelos William E. Pinchak Byeng R. Min Gordon E. Carstens Robin C. Anderson Luis O. Tedeschi 《Journal of environmental science and health. Part. B》2013,48(4):360-365
Pathogenic bacteria attached to the hide or shed in the feces of cattle at slaughter can contaminate carcasses intended to be processed for human consumption. Therefore, new pre-harvest interventions are needed to prevent the carriage and excretion of foodborne pathogens in cattle presented to the processing plant. The objectives of this study were to examine the antimicrobial effects of hydrolysable tannin-rich chestnut and condensed tannin-rich mimosa extracts on bacterial indicators of foodborne pathogens when applied as a hide-intervention and as a feed additive to feedlot cattle. Water (control) or solutions (3 % wt/vol) of chestnut- and mimosa-extract treatments were sprayed (25 mL) at the left costal side of each animal to a 1000 cm2 area, divided in four equal quadrants. Hide-swabs samples obtained at pre-, 2-min, 8-h, and 24-h post-spray application were cultured to enumerate Escherichia coli/total coliforms and total aerobic plate counts. In a second experiment, diets supplemented without (controls) or with (1.5 % of diet dry matter) chestnut- or mimosa-extracts were fed during a 42–day experimental feeding period. Weekly fecal samples starting on day 0, and rumen fluid obtained on days 0, 7, 21 or 42 were cultured to enumerate E.coli/total coliforms and Campylobacter. Tannin spray application showed no effect of treatment or post-application-time (P> 0.05) on measured bacterial populations, averaging 1.7/1.8, 1.5/1.6 and 1.5/1.7 (log10 CFU/cm2) for E. coli/total coliforms, and 4.0, 3.4 and 4.2 (log10CFU/cm2) in total aerobes for control, chestnut and mimosa treatments, respectively. Mean (± SEM) ruminal E. coli and total coliform concentrations (log10 CFU/mL) were reduced (P< 0.01) in steers fed chestnut-tannins (3.6 and 3.8 ± 0.1) in comparison with the controls (4.1 and 4.2 ± 0.1). Fecal E. coli concentrations were affected by treatment (P< 0.01), showing the highest values (log10 CFU/g) in fecal contents from mimosa-fed steers compared to controls (5.9 versus 5.6 ± 0.1 SEM, respectively). Total coliforms (log CFU/g) showed the highest values (P< 0.01) in feces from chestnut- and mimosa-fed steers (6.0 and 6.1 ± 0.1 respectively) in comparison with controls (5.7 ± 0.1). Fecal Campylobacter concentrations (log10CFU/g) were affected by treatment (P< 0.05), day (P< 0.001) and their interaction (P< 0.01) with the controls having lower concentrations than chestnut- and mimosa-fed steers (0.4, 1.0, and 0.8 ± 0.3, respectively). It was concluded that under our research conditions, tannins were not effective in decreasing measured bacterial populations on beef cattle hides. Additionally, chestnut tannin reduced E. coli and total coliforms within the rumen but the antimicrobial effect was not maintained in the lower gastrointestinal tract. Further research is necessary to elucidate the possible antimicrobial effects of tannins at site-specific locations of the gastrointestinal tract in beef cattle fed high-grain and high-forage diets. 相似文献
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40.
Mapping the Spatial Variability of Plant Diversity in a Tropical Forest: Comparison of Spatial Interpolation Methods 总被引:4,自引:0,他引:4
Hernandez-Stefanoni JL Ponce-Hernandez R 《Environmental monitoring and assessment》2006,117(1-3):307-334
Knowledge of the spatial distribution of plant species is essential to conservation and forest managers in order to identify
high priority areas such as vulnerable species and habitats, and designate areas for reserves, refuges and other protected
areas. A reliable map of the diversity of plant species over the landscape is an invaluable tool for such purposes. In this
study, the number of species, the exponent Shannon and the reciprocal Simpson indices, calculated from 141 quadrat sites sampled
in a tropical forest were used to compare the performance of several spatial interpolation techniques used to prepare a map
of plant diversity, starting from sample (point) data over the landscape. Means of mapped classes, inverse distance functions,
kriging and co-kriging, both, applied over the entire studied landscape and also applied within vegetation classes, were the
procedures compared. Significant differences in plant diversity indices between classes demonstrated the usefulness of boundaries
between vegetation types, mapped through satellite image classification, in stratifying the variability of plant diversity
over the landscape. These mapped classes, improved the accuracy of the interpolation methods when they were used as prior
information for stratification of the area. Spatial interpolation by co-kriging performed among the poorest interpolators
due to the poor correlation between the plant diversity variables and vegetation indices computed by remote sensing and used
as covariables. This indicated that the latter are not suitable covariates of plant diversity indices. Finally, a within-class
kriging interpolator yielded the most accurate estimates of plant diversity values. This interpolator not only provided the
most accurate estimates by accounting for the indices' intra-class variability, but also provided additional useful interpretations
of the structure of spatial variability of diversity values through the interpretation of their semi-variograms. This additional
role was found very useful in aiding decisions in conservation planning. 相似文献